离子表面活性剂胶团对阿斯匹林碱水解反应的影响

离子表面活性剂胶团对阿斯匹林碱水解反应的影响史振民＊刘生昆张祝莲巩育军（延安大学化学系延安７１６０００）关键词表面活性剂，阿斯匹林，碱水解反应，胶团，抑制作用１９９６－０５－０４收稿，１９９６－０８－１２修回阿斯匹林（ＡＳＰ），学名为乙酰水杨酸，有较...     

D→Klv～l衰变过程的研究

用光锥QCD求和规则研究D→Klv～_l衰变过程，首先计算D→K跃迁形状因子，通过构造新的关联函数，消除了twist-3波函数的不确定性给计算结果所带来的影响，从而使计算结果更加精确. 计算得到的分支比与最近的实验数据相一致. 关键词： QCD光锥求和规则 D介子半轻衰变 分支比 形状因子     

THE GENERALIZED MAXIMUM ANGLE CONDITION FOR THE Q1 ISOPARAMETRIC ELEMENT

We consider the quadrilateral Q1 isoparametric element and establish an optimal error estimate in H^1 norm for the interpolation operator under a weaker mesh condition which admits anisotropic quadrilaterals and allows the quadrilateral to become a regular triangle in the sense of maximum angle condition [5, 11].     

Ab initio calculations of accurate dissociation energy and analytic potential energy function for the second excited state B1∏ of 7LiH

The reasonable dissociation limit of the second excited singlet state B¹∏ of ⁷LiH molecule is obtained. The accurate dissociation energy and equilibrium geometry of the B¹\Pi state are calculated using a symmetry-adapted-cluster configuration--interaction method in full active space. The whole potential energy curve for the B¹∏ state is obtained over the internuclear distance ranging from about 0.10nm to 0.54nm, and has a least-square fit to the analytic Murrell--Sorbie function form. The vertical excitation energy is calculated from the ground state to the B¹∏ state and compared with previous theoretical results. The equilibrium internuclear distance obtained by geometry optimization is found to be quite different from that obtained by single-point energy scanning under the same calculation condition. Based on the analytic potential energy function, the harmonic frequency value of the B¹∏ state is estimated. A comparison of the theoretical calculations of dissociation energies, equilibrium interatomic distances and the analytic potential energy function with those obtained by previous theoretical results clearly shows that the present work is more comprehensive and in better agreement with experiments than previous theories, thus it is an improvement on previous theories.     

商标数据库存储模式及其检索算法研究

依据商标专家的先验知识和基于内容的图像检索技术，提出了一种新的商标库存储结构，并依据该存储结构设计了以三级检索算法为核心的实用商标登记注册管理系统，对于检索算法，一级检索采用人工确认，二级检索采用傅立叶描述子作为边缘特征向量，三级检索采用hu不变矩组作为矩特征向量，从而达到提高商标申请注册中的检索速度和查准率。     

Improved coating method for uniform polymer layer in infrared hollow fiber

An improved coating method was proposed in order to form a uniform polymer layer in the fabrication of cyclic olefin polymer-coated silver (COP/Ag) hollow fiber. A COP solution was flowed in a closed loop, in which the silver-coated tube was used as a part of the loop. Owing to the constant flowing speed of the COP solution and the airtight flowing environment, a COP layer was uniformly formed. The hollow fibers attain high performance and deliver multi-wavelength laser light from the infrared to the visible simultaneously. The method was successfully applied to the fabrication of practical hollow fibers with 2 m length for the near and mid-infrared lasers.     

光刻机投影物镜的像差原位检测新技术

提出了一种新的光刻机投影物镜像差原位检测(AMF)技术。详细分析了该技术利用特殊测试标记检测投影物镜球差、像散、彗差的基本原理,论述了该技术利用对准位置坐标计算像差引起的成像位置偏移量的方法。实验结果表明AMF技术可实现球差、彗差、像散等像差参量的精确测量。AMF技术考虑了光刻胶等工艺因素对像差引起的成像位置偏移量的影响,有效避免了目前基于硅片曝光方式的彗差原位检测技术对离焦量、像面倾斜等像质参量限制的依赖。     

线电荷串产生的史密斯-帕塞尔辐射

采用积分方法分析了线电荷串,沿周期性理想金属光栅表面平行移动时产生的史密斯帕塞尔辐射。分别对短周期光栅、低能量线电荷串与长周期光栅、高能量线电荷串的辐射情况进行了数值计算。相对单个线电荷而言,N个线电荷与反射光栅作用产生的辐射场密度,在频率是线电荷串调制频率的整数倍处出现最大,辐射谱宽变窄;随电荷能量增高,辐射能量向高频方向移动,并具有强烈的定向性;可以通过调节线电荷调制频率等参量实现辐射电磁波频率锁定。研究结果表明,对高能量与低能量的电荷参量,适当选择光栅尺寸与线电荷串间隔周期,都可使辐射波工作于太赫兹波段。     

Synthesis and application as polymer electrolyte of hyperbranched polyether made by cationic ring‐opening polymerization of 3‐{2‐[2‐(2‐hydroxyethoxy)ethoxy]ethoxymethyl}‐3′‐methyl‐oxetane

A novel cyclic ether monomer 3‐{2‐[2‐(2‐hydroxyethoxy)ethoxy]ethoxy‐methyl}‐3′‐methyloxetane (HEMO) was prepared from the reaction of 3‐hydroxymethyl‐3′‐methyloxetane tosylate with triethylene glycol. The corresponding hyperbranched polyether (PHEMO) was synthesized using BF₃·Et₂O as initiator through cationic ring‐opening polymerization. The evidence from ¹H and ¹³C NMR analyses revealed that the hyperbranched structure is constructed by the competition between two chain propagation mechanisms, i.e. active chain end and activated monomer mechanism. The terminal structure of PHEMO with a cyclic fragment was definitely detected by MALDI‐TOF measurement. A DSC test implied that the resulting polyether has excellent segment motion performance potentially beneficial for the ion transport of polymer electrolytes. Moreover, a TGA assay showed that this hyperbranched polymer possesses high thermostability as compared to its liquid counterpart. The ion conductivity was measured to reach 5.6 × 10^?5 S/cm at room temperature and 6.3 × 10^?4 S/cm at 80 °C after doped with LiTFSI at a ratio of Li:O = 0.05, presenting the promise to meet the practical requirement of lithium ion batteries for polymer electrolytes. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3650–3665, 2006     

DIRICHLET BOUNDARY VALUE PROBLEMS FOR SECOND-ORDER QUASI-LINEAR DIFFERENTIAL EQUATIONS WITH CHANGING SIGN NONLINEARITIES

This paper is concerned with the existence of positive solutions of two-point Dirichlet singular and nonsingular boundary problems for second-order quasi-linear differential equations with changing sign nonlinearities.